袁克东
2017-06-28 15:44  

袁克东副研究员

2010 本科,江南大学  

2015 博士,法国雷恩一大  

2016-至今 副研究员,天津理工大学  

电话: +86-15122425939  

邮箱:Kedong.yuan@tjut.edu.cn

研究兴趣:

基于过渡金属有机催化转化中的关键机理,探索研究纳米多孔金属材料在非均相有机催化,电化学有机合成中的应用。利用过渡金属催化C-H键活化策略对有机光电材料进行修饰改性,设计探索并优化精细化学品合成的新方法,新工艺。集中研究有机廉价小分子的高效、高附加值转化。  

代表性论文:

1.K. Yuan,F. Jiang; Z. Sahli, M. Achard, T. Roisnel, C. Bruneau*, Iridium-Catalyzed Oxidant-Free Dehydrogenative C-H bond Functionalization: Selective Preparation ofN-Arylpiperidines through Tandem Hydrogen Transfers,Angew. Chem. Int. Ed.2012,51,8876-8880.  

2.K. Yuan,H. Doucet*, Benzenesulfonyl chlorides: New reagents for access to alternative regioisomers in palladium-catalysed direct arylations of thiophenes.,Chem. Sci.2014, 5,392-396.

3.K. Yuan,J.-F. Soulé, H. Doucet*,Functionalization of C−H Bonds via Metal-Catalyzed Desulfitative Coupling: An Alternative Tool for Access to Aryl- or Alkyl-Substituted (Hetero)arenes,ACS Catal.2015,5, 978-991.

4.K. Yuan,J. Boixel,H. Le Bozec,A. Boucekkine,H. Doucet*,V. Guerchais*,D. Jacquemin*, Perfluorocyclohexene bridges in inverse DiArylEthenes: synthesis through Pd-catalysed C–H bond activation, expeimental and theoretical studies on their photoreactivity,Chem. Commun.2013,49,7896-7898.

5.K. Yuan,J. Boixel, A. Chantzis,D. Jacquemin*,V. Guerchais*,H. Doucet*, Benzothiophene or Benzofuran Bridges in DiArylEthenes: Two Steps AccessviaPd-Catalysed C-H Activations and Joint Theoretical-Experimental Studies on Their Photoreactivity.,Chem. Eur. J.2014,20, 10073-10083.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

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